ON THE INFLUENCE OF TEMPERATURE IN THE PHYSICAL AND MECHANICAL CHARACTERIZATION OF POLYMER OXIDATION PROFILES

被引：10

作者：

DOLE, P ^{[1
]}

CHAUCHARD, J ^{[1
]}

机构：

[1] UNIV LYON 1,MAT PLAST & BIOMAT LAB,CNRS,URA 507,43 BD 11 NOVEMBRE 1918,F-69622 VILLEURBANNE,FRANCE

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1994年 / 195卷 / 12期

关键词：

D O I：

10.1002/macp.1994.021951220

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The diffusion-limited thermodegradation of a poly[ethylene-co-(methyl acrylate)] rubber was studied using an original pinpoint dynamic mechanical analysis (PDMA). The importance of the temperature of the analysis in the physical and mechanical determination of oxidation profiles was clearly illustrated. The variations of the tan delta (delta: loss angle) at the glass transition temperature allows the determination of the apparent activation energy of the diffusion-limited thermo-oxidation phenomena.

引用

页码：3949 / 3961

页数：13

共 17 条

[1] PHOTO-OXIDATION OF ELASTOMERIC MATERIALS .3. PHOTOOXIDATION OF ACRYLONITRILE BUTADIENE COPOLYMER [J].

ADAM, C ;

LACOSTE, J ;

LEMAIRE, J .

POLYMER DEGRADATION AND STABILITY, 1990, 27 (01) :85-97

[2]

BELOUSOVA MV, 1985, ACTA POLYM, V10, P36

[3] INFLUENCE OF THICKNESS OF ADHESIVE LAYER AND AGING CONDITIONS ON THE DYNAMIC MECHANICAL-PROPERTIES OF A STAINLESS-STEEL EPOXY-ADHESIVE SANDWICH [J].

BOURAHLA, H ;

CHAUCHARD, J ;

LENOIR, J ;

ROMAND, M .

ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1990, 178 :47-62

[4]

CAUTHIER C, 1993, MAKROMOL CHEM, V194, P1421

[5]

CHAILAN JF, 1993, THESIS LYON

[6]

GAUTHIER C, 1991, CR ACAD SCI II, V313, P891

[7] INHOMOGENEOUS RADIATION DEGRADATION IN POLYMERS STUDIED WITH A DENSITY GRADIENT COLUMN [J].

GILLEN, KT ;

CLOUGH, RL .

RADIATION PHYSICS AND CHEMISTRY, 1983, 22 (3-5) :537-544

[8] MODULUS PROFILING OF POLYMERS [J].

GILLEN, KT ;

CLOUGH, RL ;

QUINTANA, CA .

POLYMER DEGRADATION AND STABILITY, 1987, 17 (01) :31-47

[9]

GILLEN KT, 1992, POLYM DEG STAB, V38, P47

[10]

GILLEN KT, 1991, ACS S SERIES, V475

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