SYNTHESIS AND FLUORIDE ION-TRIGGERED CHEMILUMINESCENCE (CIEEL MECHANISM) OF SILOXY-SUBSTITUTED BENZOFURAN DIOXETANES

被引：29

作者：

ADAM, W

FELL, R

SCHULZ, MH

机构：

[1] Institute of Organic Chemistry, University of Würzburg, D-8700 Würzburg, Am Hubland

来源：

TETRAHEDRON | 1993年 / 49卷 / 11期

关键词：

BENZOFURAN DIOXETANES; CIEEL; FLUORIDE ION TRIGGERING; CHEMILUMINESCENCE;

D O I：

10.1016/S0040-4020(01)80366-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The dioxetanes 2 with tert-butyldimethylsilyoxy-substituted aryl groups have been prepared from the corresponding benzofurans by photooxygenation and their fluoride ion-triggered CIEEL chemiluminescence was investigated; facile saponification by fluoride and even phenoxide ions of the aryl esters 4 is held responsible for the low chemiluminescence efficiencies.

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页码：2227 / 2238

页数：12

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