SYNTHESIS AND FLUORIDE ION-TRIGGERED CHEMILUMINESCENCE (CIEEL MECHANISM) OF SILOXY-SUBSTITUTED BENZOFURAN DIOXETANES

被引：29
作者：
ADAM, W
FELL, R
SCHULZ, MH
机构：
[1] Institute of Organic Chemistry, University of Würzburg, D-8700 Würzburg, Am Hubland
来源：
TETRAHEDRON | 1993年 / 49卷 / 11期
关键词：
BENZOFURAN DIOXETANES; CIEEL; FLUORIDE ION TRIGGERING; CHEMILUMINESCENCE;
D O I：
10.1016/S0040-4020(01)80366-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The dioxetanes 2 with tert-butyldimethylsilyoxy-substituted aryl groups have been prepared from the corresponding benzofurans by photooxygenation and their fluoride ion-triggered CIEEL chemiluminescence was investigated; facile saponification by fluoride and even phenoxide ions of the aryl esters 4 is held responsible for the low chemiluminescence efficiencies.
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页码：2227 / 2238
页数：12
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