A SESQUITERPENE FROM CELASTRUS-ROSTHORNIANUS

被引:13
作者
TU, YQ
LI, ZZ
CHEN, YZ
机构
[1] National Laboratory of Application Organic Chemistry, Department of Chemistry, Lanzhou University, Lanzhou
关键词
CELASTRUS-ROSTHORNIANUS; CELUSTRACEAE; ROOT BARK; SESQUITERPENOID; 2D NMR SPECTRA;
D O I
10.1016/0031-9422(92)80305-X
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A new sesquiterpene polyol ester, 1-beta-acetoxy-2-beta, 8-beta, 9-alpha-tribenzoyloxy-6-alpha-hydroxy-beta-dihydroagarofuran, was isolated from the root bark of Celastrus rosthornianus. Its structure was elucidated mainly on the basis of 1D and 2D NMR spectrometry. The complete assignment of the C-13 NMR chemical shifts, and the determination of H-1-H-1 weak couplings observed in the H-1 NMR spectrum were also carried out on the basis of the 2D NMR spectra.
引用
收藏
页码:1415 / 1417
页数:3
相关论文
共 12 条
[1]   2-DIMENSIONAL SPECTROSCOPY - APPLICATION TO NUCLEAR MAGNETIC-RESONANCE [J].
AUE, WP ;
BARTHOLDI, E ;
ERNST, RR .
JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (05) :2229-2246
[2]  
BAUDOUIN G, 1984, HETEROCYCLES, V22, P2221
[3]   SESQUITERPENES FROM SEEDS OF MAYTENUS-BOARIA [J].
BECERRA, J ;
GAETE, L ;
SILVA, M ;
BOHLMANN, F ;
JAKUPOVIC, J .
PHYTOCHEMISTRY, 1987, 26 (11) :3073-3074
[4]  
BRUNING R, 1978, PHYTOCHEMISTRY, V17, P1821, DOI 10.1016/S0031-9422(00)88719-1
[5]  
DENHERTO.HJ, 1974, TETRAHEDRON LETT, P2219
[6]  
JACOBSON M, 1958, AGR HDB USDA, V154, P44
[7]   ASSIGNMENT OF CARBONYL CARBONS AND SEQUENCE-ANALYSIS IN PEPTIDES BY HETERONUCLEAR SHIFT CORRELATION VIA SMALL COUPLING-CONSTANTS WITH BROAD-BAND DECOUPLING IN T1 (COLOC) [J].
KESSLER, H ;
GRIESINGER, C ;
ZARBOCK, J ;
LOOSLI, HR .
JOURNAL OF MAGNETIC RESONANCE, 1984, 57 (02) :331-336
[8]   EXPERIMENTAL-TECHNIQUES OF TWO-DIMENSIONAL CORRELATED SPECTROSCOPY [J].
NAGAYAMA, K ;
KUMAR, A ;
WUTHRICH, K ;
ERNST, RR .
JOURNAL OF MAGNETIC RESONANCE, 1980, 40 (02) :321-334
[9]  
TAKAISHI Y, 1987, CHEM PHARM BULL, V35, P3534
[10]   STRUCTURE OF 2 NEW SESQUITERPENOID INSECT ANTIFEEDANTS FROM CELASTRUS-ROSTHORNIANUS [J].
TU, YQ .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (02) :425-427