SYNTHESIS AND STRUCTURE OF LITHIUM NITRIDOTANTALATE(V) LI7TAN4

被引：30
作者：
WACHSMANN, C
JACOBS, H
机构：
[1] Universität, Fachbereich Chemie, Dortmund
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 1992年 / 190卷 / 01期
关键词：
D O I：
10.1016/0925-8388(92)90185-C
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The previously reported compound ''Li7TaN4'' [1-4] is a mixture of two phases. In addition to the already described Li16Ta2N8O [5], single crystals of the second phase identified as Li7TaN4 were obtained. Li7TaN4 (a = 9.825(2) angstrom, Z = 8, spacegroup Pa3BAR) crystallizes in a superstructure of antifluorite type. Thereby tantalum is coordinated tetrahedrally by nitrogen (first coordination sphere (CS)) and octahedrally (second CS) and cubooctahedrally (third CS) by lithium.
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页码：113 / 116
页数：4
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