AN UNUSUAL GEOMETRY OF 5-COORDINATE COPPER(II) - THE STRUCTURE OF CU(TERPY)I2 AND SPECTROSCOPIC INVESTIGATIONS OF COMPLEXES CU(TERPY)X2(X-I, NCS)

被引：21
作者：
KUTOGLU, A
ALLMANN, R
FOLGADO, JV
ATANASOV, M
REINEN, D
机构：
[1] UNIV MARBURG,FACHBEREICH GEOWISSENSCH,HANS MEERWEIN STR,W-3550 MARBURG,GERMANY
[2] UNIV VALENCIA,DEPT QUIM INORGAN,UIBCM,E-46100 BURJASSOT,SPAIN
[3] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY
[4] BULGARIAN ACAD SCI,INST GEN & INORGAN CHEM,BU-1040 SOFIA,BULGARIA
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1991年 / 46卷 / 09期
关键词：
5-COORDINATE COPPER(II); SPECTROSCOPIC INVESTIGATIONS;
D O I：
10.1515/znb-1991-0910
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure of the compound Cu(terpy)I2 (terpy 2,2':6',2'' terpyridine) was determined at room temperature. It is monoclinic, space group I2/c with a = 13.689(3), b = 9.510(2), c = 11.605(3) angstrom, beta = 97.59(4)-degrees and Z = 4. The copper(II) ions are five-coordinated by the three nitrogen atoms from the terpy ligand and the two iodine atoms. The CuN3I2 polyhedron exhibits the same unusual ''reverse'' geometry as is observed for Cu(terpy)(NCS)2. Single crystal EPR measurements of the iodide and the isothio-cyanate complexes confirmed the structural results, excluding the possibility of a dynamically averaged geometry.
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页码：1193 / 1199
页数：7
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