Crystal structure of cyclohexylammonium thiocyanate

被引：6

作者：

Bagabas, Abdulaziz A. ^{[1
]}

Alhoshan, Sultan B. ^{[1
]}

Ghabbour, Hazem A. ^{[2
]}

Kumar, C. S. Chidan ^{[3
,4
]}

Fun, Hoong-Kun ^{[2
,3
]}

机构：

[1] KACST, MSRI, NPTC, POB 6086, Riyadh 11442, Saudi Arabia

[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Riaydh 11451, Saudi Arabia

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[4] Alvas Inst Engn & Technol, Dept Chem, Moodbidri 574225, Karnataka, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; cyclohexylammonium; distorted chair; hydrogen bonding;

D O I：

10.1107/S2056989014027297

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title salt, C6H11NH3+center dot SCN-, the cyclohexylammonium ring adopts a slightly distorted chair conformation. The ammonium group occupies an equatorial position to minimize 1,3 and 1,5 diaxial interactions. In the crystal, the components are linked by N-H center dot center dot center dot N and N-H center dot center dot S hydrogen-bonding interactions, resulting in a three-dimensional network.

引用

页码：O62 / +

页数：8

共 14 条

[1] Cyclohexylammonium nitrate
Bagabas, Abdulaziz A.
Aboud, Mohamed F. A.
Shemsi, Ahsan M.
Addurihem, Emad S.
Al-Othman, Zeid A.
Kumar, C. S. Chidan
Fun, Hoong-Kun
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O253 - +
[2] NUCLEOTIDES .45. DERIVATIVES OF BETA-2-AMINO-2-DEOXY-D-GLUCOSE (BETA-D-GLUCOSAMINE) 1-PHOSPHATE
BALUJA, G
CHASE, BH
KENNER, GW
TODD, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1960, (NOV): : 4678 - 4681
[3] Bruker, 2009, SADABS APEX2 SAINT
[4] SYNTHESIS AND GAS-CHROMATOGRAPHIC STATIONARY PHASE PROPERTIES OF ALKYLAMMONIUM THIOCYANATES
CODDENS, ME
FURTON, KG
POOLE, CF
[J]. JOURNAL OF CHROMATOGRAPHY, 1986, 356 (01): : 59 - 77
[5] Goel A. B., 1988, US Patent, Patent No. [4 775 735, 4775735]
[6] Mathes R. A., 1955, US Patent, Patent No. [2 704 752, 2704752]
[7] A SYNTHESIS OF AMINE SALTS OF THIOCYANIC ACID
MATHES, RA
STEWART, FD
SWEDISH, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (10) : 3455 - 3455
[8] Morrison A. L, 1953, GB Patent, Patent No. [697 473, 697473]
[9] Packing motifs in organic ammonium carboxylate salts: extension of the ring-stacking and ring-laddering concepts
Odendal, James A.
Bruce, Jocelyn C.
Koch, Klaus R.
Haynes, Delia A.
[J]. CRYSTENGCOMM, 2010, 12 (08): : 2398 - 2408
[10] A short history of SHELX
Sheldrick, George M.
[J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122

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