SYNTHESIS OF NOVEL CARBOPOLYCYCLES AND HETEROPOLYCYCLES .17. INTRAMOLECULAR 1,3-DIPOLAR CYCLOADDITION REACTION OF 3-ENDO-AZIDO-BICYCLO[3.3.1]NON-6-ENE - A FACILE ROUTE TO 5-AZAPROTOADAMANT-4-ENE

被引：4

作者：

EGUCHI, S

SUZUKI, T

TOI, N

SASAKI, T

机构：

[1] Institute of Applied Organic Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya, 464-01, Furo-cho

来源：

HETEROCYCLES | 1990年 / 30卷 / 01期

关键词：

D O I：

10.3987/COM-89-S13

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular 1,3-dipolar cycloaddition of 3-endo-azidobicyclo[3,3.1]non-6-ene 1 proceeded on heating in toluene under reflux to afford regioselectively very unstable 1,2,3-triazoline derivative 2, which decomposed spontaneously in MeOH to give exclusively 5-azaprotoadamant-4-ene (6. © 1990.

引用

页码：237 / 241

页数：5

共 3 条

[1] SYNTHESIS OF NOVEL CARBOPOLYCYCLES AND HETEROPOLYCYCLES .19. SYNTHESIS OF 4-AZAHOMOADAMANT-4-ENE N-OXIDES AND THEIR 1,3-DIPOLAR CYCLOADDITION REACTIVITY
YU, Y
OHNO, M
EGUCHI, S
TETRAHEDRON LETTERS, 1991, 32 (37) : 4965 - 4968
[2] A Facile Synthesis of 4,6,7,8,8a,9-Hexahydropyrrolo[1,2-a][1,2,3]triazolo[1,5-d]pyrazines by a Three-Component Coupling Reaction Followed by Intramolecular 1,3-Dipolar Cycloaddition
Dhondge, Attrimuni P.
Afraj, Shakil N.
Nuzlia, Cut
Chen, Chinpiao
Lee, Gene-Hsian
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2013, 2013 (19) : 4119 - 4130
[3] EXO,EXO-4,4,12,12,16,16-HEXAKIS(TRIFLUOROMETHYL)-17-(3,3,3-TRIFLUORO-2-TRIFLUOROMETHYL-1-AZAPROPENYL)-3,11,17-TRIAZAHEPTACYCLO[12.4.1.1(6,9).0(2,13).0(3,11).0(5,10).0(15,18)]-ICOS-7-ENE FORMED VIA NOVEL 1,3-DIPOLAR CYCLOADDITION TO QUADRICYCLANE
BARLOW, MG
PRITCHARD, RG
SULIMAN, NS
TIPPING, AE
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 : 553 - 556

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