Improved knowledge of the ways in which the structures, properties and behaviour of coated materials are interrelated, as well as technical advances in the production of specific layers, constitute a basis on which new lines are developed, especially on coatings applied by the so-called PVD methods. Topical examples of protective coating concepts, often with greatly improved characteristics, are mixed-phase layers, gradient layers, multilayers, new metastable coating materials, and multiphase layers. Their preparation, structures and properties are discussed.