Bis{2-[(guanidinoimino)methyl]-phenolato-kappa N-3,N ',O}cobalt(III) chloride hemihydrate

被引：8
|
作者：
Buvaylo, Elena A. [1 ]
Kokozay, Vladimir N. [1 ]
Vassilyevaa, Olga Yu. [1 ]
Skelton, Brian W. [2 ]
机构：
[1] Taras Shevchenko Natl Univ Kyiv, Dept Inorgan Chem, 64-13 Volodymyrska St, UA-01601 Kiev, Ukraine
[2] Univ Western Australia, Ctr Microscopy Characterisat & Anal, Crawley, WA 6009, Australia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
D O I：
10.1107/S1600536813004534
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Co(C8H9N4O)(2)]Cl center dot 0.5H(2)O, is a solvatomorph of the corresponding trihydrate. Unlike in the structure of the latter compound, there are two different cations in the asymmetric unit of the title compound. The ligand molecules are deprotonated at the phenol O atom and octahedrally coordinate the Co III atoms through the azomethine N and phenolate O atoms in a mer configuration. In the crystal, the cations, chloride ions and lattice water molecules are linked by N-H center dot center dot center dot O, N-H center dot center dot center dot Cl, O-H center dot center dot center dot Cl and O-H center dot center dot center dot O interactions, forming a two-dimensional network parallel to (101).
引用
收藏
页码：M165 / +
页数：13
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