NEW PREDICTIVE EQUATION FOR THE SOLUBILITY OF SOLID N-ALKANES IN ORGANIC-SOLVENTS

被引：54
|
作者：
HAULAITPIRSON, MC
HUYS, G
VANSTRAELEN, E
机构：
[1] Univ of Leuven, Heverlee, Belg, Univ of Leuven, Heverlee, Belg
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 1987年 / 26卷 / 03期
关键词：
ALCOHOLS; -; Applications; ESTERS; HYDROCARBONS; SOLIDS; Solubility; SOLVENTS; Components;
D O I：
10.1021/ie00063a008
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
An equation was developed to predict the solubility of solid n-alkanes in organic solvents including hydrocarbons, ketones, esters, and alcohols. The principal advantage offered by this equation is the limited number of quantities needed for the calculations. Fusion and transition properties of the solid alkanes, their molar volumes, and the molar volumes of the solvents are enough for a correct prediction of the solubility in nonpolar solvents. In polar solvents, in addition to these factors, a modified, nonspecific solubility parameter for the solute and for the solvent is needed.
引用
收藏
页码：447 / 452
页数：6
相关论文
共 50 条
  • [41] CONFORMATIONAL DISORDER IN SOLID N-ALKANES
    SNYDER, RG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 197 : 139 - PMSE
  • [42] SOLUBILITY OF LIQUID-CRYSTALS IN ORGANIC-SOLVENTS
    PESTOV, SM
    MOLOTCHKO, VA
    LIDINE, RA
    THERMOCHIMICA ACTA, 1994, 236 : 131 - 139
  • [43] SOLUBILITY OF NITRYL TETRAFLUOROBORATE AND FLUOROSULFONATE IN ORGANIC-SOLVENTS
    GUK, YV
    LEGOSTAEVA, EK
    LEBEDEV, BA
    GIDASPOV, BV
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1978, 51 (11): : 2480 - 2481
  • [44] SOLUBILITY OF C-60 IN ORGANIC-SOLVENTS
    SIVARAMAN, N
    DHAMODARAN, R
    KALIAPPAN, I
    SRINIVASAN, TG
    RAO, PRV
    MATHEWS, CK
    JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (22): : 6077 - 6079
  • [45] STUDY OF N-CINNAMOYL PHENYL HYDROXYLAMINATE SOLUBILITY IN WATER AND ORGANIC-SOLVENTS
    PILIPENKO, AT
    SHPAK, EA
    SAMCHUK, AI
    UKRAINSKII KHIMICHESKII ZHURNAL, 1975, 41 (07): : 734 - 738
  • [46] W Modeling and predicting solubility of n-alkanes in water
    Safamirzaei, Mani
    Modarress, Hamid
    FLUID PHASE EQUILIBRIA, 2011, 309 (01) : 53 - 61
  • [47] DETERMINATION OF SOLUBILITY OF SOME ORGANIC-CRYSTALS IN ORGANIC-SOLVENTS
    GMELIN, K
    JOURNAL OF CRYSTAL GROWTH, 1976, 35 (02) : 236 - 238
  • [48] Solubility of water in n-alkanes: New experimental measurements and molecular dynamics simulations
    Morgado, Pedro
    Barras, Joao
    Duarte, Pedro
    Filipe, Eduardo J. M.
    FLUID PHASE EQUILIBRIA, 2020, 503
  • [49] On the solubility of long n-alkanes in water at room temperature
    Graziano, Giuseppe
    CHEMICAL PHYSICS LETTERS, 2011, 511 (4-6) : 262 - 265
  • [50] EVALUATION OF SOLVENCY OF DIFFERENT SOLVENTS IN THE CRYSTALLIZATION OF N-ALKANES
    TYUMKIN, SV
    CHEMISTRY AND TECHNOLOGY OF FUELS AND OILS, 1993, 29 (7-8) : 359 - 360
12345