TRANSFORMATION OF ACYLOIN O-ACYL DERIVATIVES TO KETONES USING TETRABUTYLAMMONIUM FLUORIDE-THIOL SYSTEM

被引：9

作者：

UEKI, M

OKAMURA, A

YAMAGUCHI, J

机构：

[1] Department of Applied Chemistry, Faculty of Science, Science University of Tokyo, Shinjuku-ku, Tokyo, 162

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 41期

关键词：

D O I：

10.1016/0040-4039(95)01597-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The treatment of acyloin (alpha-hydroxyketone) O-acyl derivatives with tetrabutylammonium fluoride hydrate (TBAF . xH(2)O)-1,3-propanedithiol system gave the corresponding ketones. Further, it was found that N-methylmorpholine added could prevent the concomitant of unidentified compounds to give the pure products in high yields.

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页码：7467 / 7470

页数：4

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