TOWARDS NOVEL ORGANIC-SYNTHESIS ON MULTIMETALLIC CENTERS - SYNTHESES AND REACTIVITIES OF DINUCLEAR RUTHENIUM THIOLATE COMPLEXES

被引：69

作者：

HIDAI, M

MIZOBE, Y

MATSUZAKA, H

机构：

[1] Department of Synthetic Chemistry, The University of Tokyo, Hongo, Tokyo

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 473卷 / 1-2期

关键词：

RUTHENIUM; THIOLATE; ALKYNE; CLUSTER; METALLACYCLE; OXIDATIVE ADDITION;

D O I：

10.1016/0022-328X(94)80099-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

From the reactions of [Cp*RuCl(mu2-Cl)2RuCp*Cl] (CP* = eta5-C5Me5) with thiolate compounds, four types of thiolate-bridged diruthenium complexes have been obtained depending upon the thiolate source. These diruthenium complexes serve not only as a potential precursor for the synthesis of dinuclear disulfide-thiolate complexes and mixed-metal sulfide-thiolate clusters but also provide unique bimetallic reaction sites for the activation and transformations of various substrates such as alkynes, organic halides and H-2.

引用

页码：1 / 14

页数：14

共 48 条

[41] TRANSITION-METAL DIENE COMPLEXES IN ORGANIC-SYNTHESIS .3. IRON-MEDIATED DIASTEREOSELECTIVE SPIROANNELATION TO THE SPIRO[1,2,3,4-TETRAHYDROQUINOLINE-4,1'-CYCLOHEXANE] SYSTEM AND A NOVEL REARRANGEMENT TO 2,3-DIHYDROINDOLE DERIVATIVES
KNOLKER, HJ
BOESE, R
HARTMANN, K
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (12): : 1678 - 1679
[42] Novel concepts in directed biaryl synthesis, 68 -: Enantioselective organic syntheses using chiral transition metal complexes, 9 -: Atropo-diastereoselective ring opening of biaryl thionolactones using [CpRu{(S,S)-CHIRAPHOS}]+ as a chiral auxiliary
Schenk, WA
Kümmel, J
Reuther, I
Burzlaff, N
Wuzik, A
Schupp, O
Bringmann, G
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 1999, (10) : 1745 - 1756
[43] TRANSITION-METAL DIENE COMPLEXES IN ORGANIC-SYNTHESIS .6. STEREOSELECTIVE SYNTHESIS OF IRON-COMPLEXED 4B,8A-DIHYDROCARBAZOL-3-ONES - A NOVEL ROUTE TO 4A,9A-DIHYDRO-9H-CARBAZOLES AND HIGHLY CHEMOSELECTIVE, REGIOSELECTIVE, AND STEREOSELECTIVE SAKURAI REACTIONS
KNOLKER, HJ
JONES, PG
PANNEK, JB
WEINKAUF, A
SYNLETT, 1991, (03) : 147 - 150
[44] ORGANIC-CHEMISTRY OF DINUCLEAR METAL CENTERS .7. YLIDES IN THE SYNTHESIS OF ORGANODIRUTHENIUM COMPLEXES - X-RAY CRYSTAL-STRUCTURE OF [RU2(CO)2(MU-CO)(MU-CH2)(ETA-C5H5)2]
DAVIES, DL
KNOX, SAR
MEAD, KA
MORRIS, MJ
WOODWARD, P
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (10): : 2293 - 2299
[45] SYNTHESIS OF DINUCLEAR IRON AND RUTHENIUM AMINOALKYLIDENE COMPLEXES AND THE MOLECULAR-STRUCTURE OF THE NOVEL CIS-[RU-2(CO)(2)(CP)(2)(MU-C(CN)N(ME)BZ)(2)] (CP=ETA-C5H5 BZ=CH(2)PH)
ALBANO, VG
BUSETTO, L
CARLUCCI, L
CASSANI, MC
MONARI, M
ZANOTTI, V
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) : 133 - 139
[46] Reactivity of the dimer [{Ru(η3:η3-C10H16)(μ-Cl)Cl}2] towards diphosphines and diphosphine-monoxides:: synthesis and characterization of novel (2,7-dimethylocta-2,6-diene-1,8-diyl)-ruthenium(IV) complexes
Cadierno, V
García-Garrido, SE
Gimeno, J
INORGANICA CHIMICA ACTA, 2003, 347 : 41 - 48
[47] NOVEL REACTIONS OF ALKYNES ON DINUCLEAR RUTHENIUM CENTERS BRIDGED BY THIOLATE LIGANDS - SYNTHESES AND CHARACTERIZATION OF (ETA-5-C5ME5)RU(MU-2-H)-(MU-2-SPRI)[ETA-2-MU-2-ME3SICCC(=CHSIME3)CCSIME3]RU(ETA-5-C5ME5) AND (ETA-5-C5ME5)RU(CCTOL)(MU-2-SPRI)2RU(CCTOL)(ETA-5-C5ME5)
MATSUZAKA, H
MIZOBE, Y
NISHIO, M
HIDAI, M
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (15) : 1011 - 1012
[48] Synthesis, structure and reactivities of the dinuclear μ-η1:η6-arylethynyl ruthenium complexes [Cp(PR3)2Ru(μ-η1:η6-C≡CC6H4Me-p)RuCp*]•Cl (R = Ph, Me; Cp = η5-C5H5, Cp* = η5-C5Me5).: The molecular structure of [Cp(PPh3)2Ru(μ-η1:η6-C≡CC6H4Me-p)RuCp*]•PF6
Matsuzaka, H
Okimura, H
Sato, Y
Ishii, T
Yamashita, M
Kondo, M
Kitagawa, S
Shiro, M
Yamasaki, M
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 625 (02) : 133 - 139

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