TOWARDS NOVEL ORGANIC-SYNTHESIS ON MULTIMETALLIC CENTERS - SYNTHESES AND REACTIVITIES OF DINUCLEAR RUTHENIUM THIOLATE COMPLEXES

被引：69
|
作者：
HIDAI, M
MIZOBE, Y
MATSUZAKA, H
机构：
[1] Department of Synthetic Chemistry, The University of Tokyo, Hongo, Tokyo
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 473卷 / 1-2期
关键词：
RUTHENIUM; THIOLATE; ALKYNE; CLUSTER; METALLACYCLE; OXIDATIVE ADDITION;
D O I：
10.1016/0022-328X(94)80099-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
From the reactions of [Cp*RuCl(mu2-Cl)2RuCp*Cl] (CP* = eta5-C5Me5) with thiolate compounds, four types of thiolate-bridged diruthenium complexes have been obtained depending upon the thiolate source. These diruthenium complexes serve not only as a potential precursor for the synthesis of dinuclear disulfide-thiolate complexes and mixed-metal sulfide-thiolate clusters but also provide unique bimetallic reaction sites for the activation and transformations of various substrates such as alkynes, organic halides and H-2.
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页码：1 / 14
页数：14
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