ADDITION-FRAGMENTATION CHAIN TRANSFER IN FREE-RADICAL STYRENE POLYMERIZATION IN THE PRESENCE OF 2,4-DIPHENYL-4-METHYL-1-PENTENE

被引：33

作者：

WATANABE, Y ^{[1
]}

ISHIGAKI, H ^{[1
]}

OKADA, H ^{[1
]}

SUYAMA, S ^{[1
]}

机构：

[1] NOF CORP, FINE CHEM & POLYMERS RES LAB, TAKETOYO CHO, AICHI 47023, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 07期

关键词：

D O I：

10.1246/cl.1993.1089

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal polymerization of styrene in the presence of 2,4-diphenyl-4-methyl-1-pentene (alpha-MSD) gave a low molecular weight polymer having a terminal double bond and a cumyl moiety without lowering the polymerization rate. A chain transfer mechanism through addition-fragmentation reaction is presented.

引用

页码：1089 / 1092

页数：4

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