SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF THE COBALT(III) COMPLEX OF 6-METHYL-6-(4-AMINO-2-AZABUTYL)-1-THIA-4-AZACYCLOHEPTANE (ATAC), CIS-[CO(ATAC)CL2]CLO4-1/2H2O

被引：2

作者：

DONLEVY, TM

GAHAN, LR

HAMBLEY, TW

机构：

[1] UNIV QUEENSLAND,DEPT CHEM,BRISBANE,QLD 4072,AUSTRALIA

[2] UNIV SYDNEY,SCH CHEM,SYDNEY,NSW 2006,AUSTRALIA

来源：

POLYHEDRON | 1993年 / 12卷 / 13期

关键词：

D O I：

10.1016/S0277-5387(00)87067-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of cis-[Co(atac)Cl2]ClO4.1./2H2O [atac = 6-methyl-6-(4-amino-2-azabutyl)-1-thia-4-azacycloheptane] has been determined by X-ray diffraction methods. The tetradentate ligand atac contains the N3S donor set and is coordinated to cobalt(III) through a secondary amine and a thioether in the cycloheptane ring, and through a pendant primary amine. The chloro ligands coordinated in a cis arrangement make up the octahedral environment of the metal ion.

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页码：1593 / 1597

页数：5

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