ADSORPTION AND TRANSPORT OF WATER IN MESOPOROUS SILICA-ADSORPTION MEASUREMENTS AND MOLECULAR SIMULATIONS

被引:1
|
作者
Daiguji, Hirofumi [1 ,2 ]
Yamashita, Kyohei [2 ]
Yanagihara, Hideki [2 ]
Endo, Akira [3 ]
机构
[1] Univ Tokyo, Dept Mech Engn, Bunkyo Ku, 7-3-1 Hongo, Tokyo 1138656, Japan
[2] Univ Tokyo, Dept Human & Engn Environm Studies, Kashiwa, Chiba 2778563, Japan
[3] Natl Inst Adv Ind Sci & Technol, AIST Tsukuba Cent 5 2, Tsukuba, Ibaraki 3058565, Japan
关键词
nano/micro-scale measurement and simulation; molecular transport; capillary condensation; capillary evaporation; diffusion; capillary action; adsorption measurement;
D O I
10.1615/SpecialTopicsRevPorousMedia.2015012208
中图分类号
TH [机械、仪表工业];
学科分类号
0802 ;
摘要
The adsorption-desorption isotherms and relaxation rates of water in Zr-doped two-dimensional hexagonal mesoporous silica with pore diameters of 3.8 nm were measured at 298 K using a gravimetric method. A type V adsorption-desorption isotherm with significant hysteresis was obtained. The adsorption layer was formed on the pore surface at low relative pressure of water vapor, capillary condensation was initiated at around 0.5 relative humidity, and then pore filling was completed near the saturated vapor pressure. The relaxation rate of water uptake in the capillary condensation state was much lower than that in the layer-adsorption state or pore-filling state. The isotherms and relaxation rates during desorption had a similar trend. In the capillary condensation and evaporation states, the relaxation curve could be estimated by the Fickian diffusion equation at a small stepwise change in relative humidity, while it could be estimated by the Lucas-Washburn law at a large stepwise change in relative humidity. Molecular simulations of water uptake in a nanopore could reproduce the trend of the relaxation curves successfully.
引用
收藏
页码:109 / 120
页数:12
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