MICROWAVE-SPECTRUM AND CONFORMATION OF 1,3-CYCLOHEPTADIENE

被引：18

作者：

AVIRAH, TK ^{[1
]}

MALLOY, TB ^{[1
]}

COOK, RL ^{[1
]}

机构：

[1] MISSISSIPPI STATE UNIV,DEPT CHEM,STATE COLL,MS 39762

来源：

JOURNAL OF CHEMICAL PHYSICS | 1979年 / 71卷 / 05期

关键词：

D O I：

10.1063/1.438601

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The microwave spectrum of 1,3-cycloheptadiene has been studied. The ground state and a number of excited vibrational states have been assigned and the rotational constants evaluated. A study of the Stark effect has yielded the dipole moment components for the ground state and two of the excited vibrational states. The total dipole moment for the ground state is 0.740 D. These data have been used to determine the conformation of 1,3-cycloheptadiene. The carbon skeleton is planar except for the C6 carbon atom, (C5 form). © 1979 American Institute of Physics.

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页码：2194 / 2201

页数：8

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