CRACKING REACTIONS OF C6 PARAFFINS ON HZSM-5

被引：42
作者：
ABBOT, J
机构：
[1] Chemistry Department, University of Tasmania, TAS
来源：
APPLIED CATALYSIS | 1990年 / 57卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
D O I：
10.1016/S0166-9834(00)80727-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cracking reactions on HZSM-5 at 500°C have been studied for n-hexane, 2-methylpentane, 3-methylpentane and 2,3-dimethylbutane. A detailed examination of selectivity and kinetic phenomena is consistent with a cracking mechanism initiated via protonation of the paraffins at Brønsted sites. The study also reveals that previous conclusions based on the "α-test" and "constraint index" may need to be re-examined. © 1990.
引用
收藏
页码：105 / 125
页数：21
相关论文
共 37 条
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