(E)-3-{[([1,10-Biphenyl]-3-ylmethyl)iminiumyl]methyl}-6,8-dichloro-2Hchromen-4-olate

被引:1
作者
Ishikawa, Yoshinobu [1 ]
Motohashi, Yuya [1 ]
机构
[1] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, 52-1 Yada, Shizuoka 4228526, Japan
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词
D O I
10.1107/S160053681302285X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the crystal of the title compound, C23H17Cl2NO2, the H atom of the -OH group is transferred to the N atom of the imine, forming a zwitterion. This results in a six-membered intramolecular O center dot center dot center dot H-N hydrogen-bonded ring, rather than that formed with an O-H center dot center dot center dot N hydrogen bond. The dihedral angle between the rings of the biphenyl unit is 13.88 (10)degrees. In the crystal, molecules are linked by N-H center dot center dot center dot O and C-H center dot center dot center dot O interactions.
引用
收藏
页码:O1448 / +
页数:8
相关论文
共 9 条
  • [1] 1-(4-Hydroxyphenyl)-2-(2-oxidonaphthalen- 1-yl) diazen-1-ium methanol hemisolvate
    Benaouida, Mohamed Amine
    Chetioui, Souheyla
    Bouaoud, Salah Eddine
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O867 - +
  • [2] 3-[(E)-(Benzyliminiumyl)methyl]-6,8-dichloro-2H-chromen-4-olate
    Ishikawa, Yoshinobu
    Motohashi, Yuya
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1225 - +
  • [3] (E)-6,8-Dichloro-3-{[(naphthalen-1-ylmethyl) iminiumyl]methyl}-2H-chromen-4-olate
    Ishikawa, Yoshinobu
    Motohashi, Yuya
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1226 - +
  • [4] Schiff bases of 3-formylchromone as thymidine phosphorylase inhibitors
    Khan, Khalid Mohammed
    Ambreen, Nida
    Hussain, Sajjad
    Perveen, Shahnaz
    Choudhary, M. Iqbal
    [J]. BIOORGANIC & MEDICINAL CHEMISTRY, 2009, 17 (08) : 2983 - 2988
  • [5] 3-[(1-Benzylamino)ethylidene]-2H-chromene-2,4(3H)-dione
    Malecka, Magdalena
    Budzisz, Elzbieta
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O5058 - O5060
  • [6] Rigaku, 2010, CRYSTALSTRUCTURE
  • [7] Rigaku, 1999, WINAFC DIFFR CONTR S
  • [8] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [9] Design and syntheses of novel N′-((4-oxo-4H-chromen-3-yl) methylene) benzohydrazide as inhibitors of cyanobacterial fructose-1,6-/sedoheptulose-1,7-bisphosphatase
    Tu, Qi-Dong
    Li, Ding
    Sun, Yao
    Han, Xin-Ya
    Yi, Fan
    Sha, Yibamu
    Ren, Yan-Liang
    Ding, Ming-Wu
    Feng, Ling-Ling
    Wan, Jian
    [J]. BIOORGANIC & MEDICINAL CHEMISTRY, 2013, 21 (11) : 2826 - 2831