INFLUENCE OF TEMPERATURE ON KINETICS OF GELATIN-CATALYZED HYDROLYSIS OF PARA-NITROPHENYL ACETATE IN LIQUID AND FROZEN-SOLUTIONS

被引：0

作者：

SERGEEV, BM

KONSTANTINOVA, NP

SERGEEV, GB

机构：

来源：

KINETICS AND CATALYSIS | 1991年 / 32卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic study of gelatin-catalyzed hydrolysis of p-nitrophenyl acetate has been carried out in the 246-345 K interval. The observed initial reaction rate in frozen samples has been found to correlate with the content of nonfreezing water at the temperature of the experiment and with the composition of the frozen solution. The observed increase in effective activation energy of hydrolysis upon freezing is explained by an increasingly important role of intermolecular interactions in the kinetics of the reactions taking place with the participation of macromolecules in water-polymer systems that are capable of cryostructurization.

引用

页码：953 / 958

页数：6

共 27 条

[1] Influence of temperature on kinetics of gelatin-catalyzed hydrolysis of p-nitrophenyl acetate in liquid and frozen solutions
Sergeev, B.M.
Konstantinova, N.P.
Sergeev, G.B.
Kinetics and Catalysis, 1992, 32 (5 pt 1) : 953 - 958
[2] INFLUENCE OF TEMPERATURE AND PARTIAL CRYSTALLIZATION OF REACTION-MIXTURE COMPONENTS ON RATE OF PARA-NITROPHENYL ACETATE HYDROLYSIS IN FROZEN-SOLUTIONS
SERGEEV, GB
SERGEEV, BM
KALNINA, IA
KINETICS AND CATALYSIS, 1983, 24 (06) : 1116 - 1122
[3] KINETICS OF THE HYDROLYSIS OF PARA-NITROPHENYL ACETATE IN FROZEN HYDROCHLORIC-ACID SOLUTIONS
SERGEEV, GB
SERGEEV, BM
KONSTANTINOVA, NR
KINETICS AND CATALYSIS, 1985, 26 (02) : 248 - 252
[4] CHANGES IN PH OF MEDIUM UPON FREEZING, AND KINETICS OF ACID-BASE HYDROLYSIS OF PARA-NITROPHENYL ACETATE IN FROZEN-SOLUTIONS
SERGEEV, GB
SERGEEV, BM
KALNINA, IA
BATYUK, VA
KINETICS AND CATALYSIS, 1983, 24 (02) : 284 - 289
[5] THE TRYPSIN CATALYZED HYDROLYSIS OF PARA-NITROPHENYL ACETATE
STEWART, JA
OUELLET, L
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1959, 37 (04): : 751 - 759
[6] KINETICS OF HYDROLYSIS OF PARA-NITROPHENYL ACETATE IN FROZEN SUSPENSIONS OF SILICA-GEL
SERGIEV, GV
SERGIEV, BM
KONSTANTINOVA, NR
KINETICS AND CATALYSIS, 1986, 27 (06) : 1281 - 1283
[7] THE IMIDAZOLE-CATALYZED HYDROLYSIS OF PARA-NITROPHENYL ACETATE
BENDER, ML
TURNQUEST, BW
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (07) : 1652 - 1655
[8] HYDROLYSIS OF PARA-NITROPHENYL ACETATE IN LIQUID AND FROZEN AQUEOUS ALCOHOL-SOLUTIONS OF HYDROCHLORIC-ACID
SERGEEV, GB
SERGEEV, BM
KONSTANTINOVA, NR
KINETICS AND CATALYSIS, 1985, 26 (01) : 24 - 28
[9] THE ALPHA-CHYMOTRYPSIN CATALYZED HYDROLYSIS OF PARA-NITROPHENYL ACETATE
MARINI, MA
HESS, GP
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (19) : 5160 - 5165
[10] Effect of gelatin on the kinetics of hydrolysis of p-nitrophenyl acetate in frozen aqueous solutions
Sergeev, B.M.
Konstantinova, N.R.
Sergeev, G.B.
Kinetics and Catalysis, 1991, 31 (5 pt 1) : 978 - 983

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