METAL-COMPLEXES OF BIOLOGICALLY IMPORTANT LIGANDS, .57. 1-SELENOGLUCOSE AS LIGAND IN METAL-COMPLEXES

被引：16
|
作者：
PILL, T
BREU, W
WAGNER, H
BECK, W
机构：
[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,W-8000 MUNICH 2,GERMANY
[2] UNIV MUNICH,INST PHARMAZEUT BIOL,W-8000 MUNICH 2,GERMANY
来源：
CHEMISCHE BERICHTE | 1991年 / 124卷 / 04期
关键词：
TRANSITION METAL COMPLEXES WITH 1-SELENOGLUCOSE; GLUCOSE AS LIGAND; SELENOGLUCOSE; CARBOHYDRATES;
D O I：
10.1002/cber.19911240407
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reactions of the in situ-prepared anion of acetylated 1-selenoglucose with chloro complexes give the compounds R'3 PAuSeR (R' = Me, Et, Ph), cis-(Ph3P)2Pt(SeR)2 and (eta-5-C5H5)2Ti(SeR)2 (SeR = 2,3,4,6-tetra-O-acetyl-1-seleno-beta-D-glucopyranosato-Se). The complexes (eta-5-C5H5)(OC)2FeSeR and (OC)3M(mu-SeR)2M(CO)3 (M = Fe, Ru) are prepared by the reaction of the diselenide RSeSeR with the dinuclear compound [eta-5-C5H5Fe(CO)2]2 and M3(CO)12 (M = Fe, Ru), respectively.
引用
收藏
页码：713 / 717
页数：5
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