A HIGH-RESOLUTION STUDY OF THE B(2)SIGMA(+)-X(2)SIGMA+ TRANSITION OF THE PN+ MOLECULAR ION

被引：10

作者：

AHMAD, IK

HAMILTON, PA

机构：

[1] Department of chemistry, Queen Mary and Westfield College, London, E1 4NS, Mile End Road

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1994年 / 163卷 / 01期

关键词：

D O I：

10.1006/jmsp.1994.1018

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The B2Σ+ - X2Σ+ emission spectrum of PN+ has been recorded at rotational resolution for the first time. Seven intense hands were rotationally analyzed over the 305- to 370-nm region to determine the rotational constants of the v′ = 0, 1, 2 and v″ 0, 1, 2, 3 levels. Maximum entropy deconvolution procedures were applied to the spectra and gave a significant improvement in the molecular parameters determined. Rotational perturbations were observed in all upper slate vibrational levels. © 1994 Academic Press, Inc.

引用

页码：214 / 220

页数：7

共 12 条

[1] VACUUM UV PHOTOELECTRON-SPECTRUM OF PN(CHI1SIGMA+) MOLECULE [J].