HEPTANUCLEAR CLUSTERS OF OSMIUM - CRYSTAL-STRUCTURE OF [OS7(CO)20P(OME)3]

被引:7
作者
JOHNSON, BFG
LEWIS, J
LUNISS, J
BRAGA, D
GREPIONI, F
机构
[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND
[2] DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY
关键词
D O I
10.1016/0022-328X(91)86239-M
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The structure of [Os7(CO)20P(OMe)3] has been determined by an X-ray diffraction study. The metal-atom skeleton consists of a capped octahedron, in which the capping Os-atom bears the P(OMe)3 ligand and two terminal COs, while the other six Os-atoms bear three terminal COs each.
引用
收藏
页码:C46 / C49
页数:4
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