LEVOGLUCOSENONE - OLD BUT NEW OPTICALLY-ACTIVE STARTING MATERIAL

被引：9
作者：
EBATA, T
MATSUSHITA, H
机构：
[1] JAPAN TOBACCO INC., Life Science Research Laboratory
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1994年 / 52卷 / 12期
关键词：
LEVOGLUCOSENONE; BAEYER-VILLIGER OXIDATION; WHISKEY LACTONE; GRANDISOL; D-ALTROSE; D-ALLOSE; OSMIUM OXIDATION;
D O I：
10.5059/yukigoseikyokaishi.52.1074
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Levoglucosenone [1,6-anhydro-3,4-dideoxy-beta-D-glycero-hex-3-eno-pyrano-2-ulose, (4)] is widely known as a pyrolytic product of cellulose. It is very useful chiral source for synthesizing natural products owing to its highly functionalized structure containing essentially one chiral center. The synthesis of useful compounds starting from levoglucosenone (4) and their applications as useful chiral building blocks are reviewed in this article.
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页码：1074 / 1082
页数：9
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