DIISOPROPYL TARTRATE MODIFIED (E)-GAMMA-[(CYCLOHEXYLOXY)DIMETHYLSILYL]-ALLYLBORONATE, A CHIRAL REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF ANTI 1,2-DIOLS VIA THE FORMAL ALPHA-HYDROXYALLYLATION OF ALDEHYDES

被引：36
作者：
ROUSH, WR
GROVER, PT
LIN, XF
机构：
[1] Department of Chemistry Indiana University, Bloomington
来源：
TETRAHEDRON LETTERS | 1990年 / 31卷 / 52期
关键词：
D O I：
10.1016/S0040-4039(00)97299-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An enantioselective synthesis of anti 1,2-diols via the reactions of aldehydes and the tartrate ester modified gamma-(alkoxysilyl)allylboronate 2 has been developed. This method is most effective in double asymmetric reactions with chiral aldehydes.
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页码：7563 / 7566
页数：4
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