SYNTHESIS, STRUCTURE, AND DYNAMICS OF ENDO-(STARPHENYLENE)CHROMIUM TRICARBONYL DERIVATIVES - OBSERVATION OF METAL ARENE MIGRATION AND HINDERED METAL-TRIPOD ROTATION

被引：42

作者：

NAMBU, M

MOHLER, DL

HARDCASTLE, K

BALDRIDGE, KK

SIEGEL, JS

机构：

[1] UNIV CALIF SAN DIEGO, DEPT CHEM, LA JOLLA, CA 92093 USA

[2] SAN DIEGO SUPERCOMP CTR, LA JOLLA, CA 92137 USA

[3] UNIV CALIF BERKELEY, BERKELEY, CA 94720 USA

[4] CALIF STATE UNIV NORTHRIDGE, NORTHRIDGE, CA 91330 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 14期

关键词：

D O I：

10.1021/ja00067a032

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dynamic stereochemistry of endo-(starphenylene)chromium tricarbonyl, endo-1-Cr, is elucidated through NMR spectroscopic methods. Intramolecular metal-arene migration and hindered metal-tripod rotation are observed in closely related derivatives of endo-1-Cr. The stereochemistry of these systems is modeled well by ab initio local density functional theory methods.

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页码：6138 / 6142

页数：5

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