ESTIMATION OF DEGREE OF SKELETON NICKEL CATALYST DEACTIVATION AT LIQUID-PHASE HYDROGENATION OF SUBSTITUTED NITROBENZENES

被引：0

作者：

Smirnova, I. V. ^{[1
]}

Nemtzeva, M. P. ^{[1
]}

Lefyodova, O. V. ^{[1
]}

Lukovitsina, M. K. ^{[1
]}

机构：

[1] Ivanovo State Univ Chem Technol, Dept Phys & Colloid Chem, Ivanovo, Russia

来源：

IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA | 2012年 / 55卷 / 01期

关键词：

deactivation; skeleton nickel catalyst; substituted nitrobenzenes; liquid-phase hydrogenation;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of skeleton nickel catalyst amount on the hydrogenation rate of substituted nitrobenzenes was studied. The main reason of the reaction rate decrease under low catalyst content was established to be the high oxibility ability of the nitrogroup. The estimation methodology of degree of skeleton nickel catalyst deactivation at liquid-phase hydrogenation of substituted nitrobenzenes was proposed.

引用

页码：51 / +

页数：6

共 50 条

[21] Effect of Controlled Deactivation on the Properties of a Supported Nickel Catalyst in the Reactions of Liquid-Phase Hydrogenation of Carbon-Carbon Multiple Bonds
Afineevskii, A. V.
Prozorov, D. A.
Knyazev, A. V.
Nikitin, K. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2021, 91 (12) : 2613 - 2620
[22] The influence of the nature of substituents on adsorbability and the rate of liquid-phase hydrogenation of nitrobenzenes
Lefedova, O. V.
Smirnova, I. V.
Nemtseva, M. P.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 83 (10) : 1727 - 1730
[23] KINETICS OF THE LIQUID-PHASE HYDROGENATION OF PHENOL TO CYCLOHEXANOL OVER A NICKEL CHROMIUM CATALYST
PALKIN, PN
KONYUKHOV, VY
GOSTIKIN, VP
TEMKIN, MI
KINETICS AND CATALYSIS, 1983, 24 (06) : 1181 - 1184
[24] DEACTIVATION OF THE CATALYST OF LIQUID-PHASE HYDROGENATION OF BENZOIC-ACID BY SUPPORTED SILICON-COMPOUNDS
KONYUKHOV, VY
KINETICS AND CATALYSIS, 1994, 35 (03) : 355 - 357
[25] Insights into deactivation mechanism of Pd@CN catalyst in the liquid-phase hydrogenation of phenol to cyclohexanone
Hu, Shuo
Zhang, Xiang
Qu, Zhengyan
Jiang, Hong
Liu, Yefei
Huang, Jun
Xing, Weihong
Chen, Rizhi
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2017, 53 : 333 - 340
[26] COMPARATIVE-STUDY ON CATALYTIC PROPERTIES AND DEACTIVATION OF (UN)SUPPORTED NICKEL FOR LIQUID-PHASE HYDROGENATION
ALPHONSE, P
MOYEN, F
RAMALANJAONA, M
MAURET, P
JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1990, 87 (06) : 1069 - 1081
[27] Kinetics of the liquid-phase hydrogenation of benzene and some monosubstituted alkylbenzenes over a nickel catalyst
Toppinen, S.
Rantakyla, T.-K.
Salmi, T.
Aittamaa, J.
Industrial and Engineering Chemistry Research, 1996, 35 (06): : 1824 - 1833
[28] Kinetics of the liquid-phase hydrogenation of benzene and some monosubstituted alkylbenzenes over a nickel catalyst
Toppinen, S
Rantakyla, TK
Salmi, T
Aittamaa, J
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (06) : 1824 - 1833
[29] LIQUID-PHASE HYDROGENATION ALDEHYDE AMINATION WITH NITROBENZENE IN THE PRESENCE OF HETEROGENEOUS NICKEL-CATALYST
SAVVATEEV, OP
KLYUEV, MV
ERYKALOV, YG
IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1987, 30 (12): : 29 - 32
[30] Reaction kinetics of the liquid-phase hydrogenation of benzonitrile to benzylamine using Raney nickel catalyst
Bawane, SP
Sawant, SB
CHEMICAL ENGINEERING JOURNAL, 2004, 103 (1-3) : 13 - 19

← 1 2 3 4 5 →