COMPLEXATION OF ENANTIOMER-FREE CIS-3-DIPHENYLPHOSPHINO-4-HYDROXYTETRAHYDROFURANS AND TRANS-3-DIPHENYLPHOSPHINO-4-HYDROXYTETRAHYDROFURANS WITH [RH(COD)(2)]BF4

被引：19

作者：

BORNER, A ^{[1
]}

KLESS, A ^{[1
]}

HOLZ, J ^{[1
]}

BAUMANN, W ^{[1
]}

TILLACK, A ^{[1
]}

KADYROV, R ^{[1
]}

机构：

[1] UNIV ROSTOCK,MAX PLANCK GESELL,ARBEITSGRP KOMPLEXKATALYSE,D-18055 ROSTOCK,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 490卷 / 1-2期

关键词：

HYDROXYALKYL PHOSPHINES; RHODIUM; NUCLEAR MAGNETIC RESONANCE; HYDROGENATION; ALCOHOL; PHOSPHINE;

D O I：

10.1016/0022-328X(94)05178-E

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexation behaviour of cis- und trans-3-diphenylphosphino-4-hydroxyl-tetrahydrofurans with [Rh(COD)(2)]BF4 is studied with the help of NMR and IR spectroscopy. In dependence of the spatial arrangement of hydroxyl and phosphino group the formation of different intra- and intermolecular bridged O-P complexes has been observed.

引用

页码：213 / 219

页数：7

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