SURPRISING BASICITY OF LOW VALENT TRANSITION-METAL CARBONYL FLUORIDES - CRYSTALLOGRAPHIC CHARACTERIZATION OF AN SP2-CH=F HYDROGEN-BOND

被引：55

作者：

OSTERBERG, CE ^{[1
]}

KING, MA ^{[1
]}

ARIF, AM ^{[1
]}

RICHMOND, TG ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199008881

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Realization of molecular recognition with transition metal complexes via exploitation of CHFM and/or OHFM hydrogen bonds—this aim is approached by the result that was observed with the WII‐complex 1, which proves to be a surprisingly strong Lewis base that binds 4‐chlorophenol equally as well as pyridine. The solid‐state packing of an analogue of 1 fluorinated in the aryl ring is characterized by hydrogen bonds between imine‐CH and fluoroligands. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：888 / 890

页数：3

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