SYNTHESIS, CHARACTERIZATION AND ELECTRICAL-PROPERTIES OF THE NOVEL POLYMER ELECTROLYTES BASED ON POLYESTERS CONTAINING ETHYLENE-OXIDE MOIETY

被引：14

作者：

KIM, DW ^{[1
]}

SONG, JS ^{[1
]}

PARK, JK ^{[1
]}

机构：

[1] KOREA ADV INST SCI & TECHNOL,DEPT CHEM ENGN,TAEJON 305701,SOUTH KOREA

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 11期

关键词：

ALIPHATIC POLYESTER; ETHYLENE OXIDE; IONIC CONDUCTIVITY; LITHIUM PERCHLORATE; POLYMER ELECTROLYTE;

D O I：

10.1016/0013-4686(95)00078-S

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The relationship between the structure and ionic conductivities of the polymer electrolytes formed with the aliphatic polyesters containing a different number of ethylene oxide (EO) units and lithium perchlorate has been investigated. These complexes were observed to be completely amorphous and showed the ionic conductivities up to 10(-5) similar to 10(-4)S/cm at 25 degrees C. The main factor that affects the ionic conductivity in these systems was proved to be a solvating capacity of the matrix polymer caused by the difference in the density of polar groups.

引用

页码：1697 / 1700

页数：4

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