SYNTHESIS AND ELECTROCONDUCTIVITIES OF POLY(2-METHOXY-5-METHYTHIO-1,4-PHENYLENE VINYLENE) AND COPOLYMERS

被引：21

作者：

JIN, JI ^{[1
]}

PARK, CK ^{[1
]}

SHIM, HK ^{[1
]}

机构：

[1] KOREA ADV INST TECHNOL,DEPT CHEM,TAEJON 305701,SOUTH KOREA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1991年 / 29卷 / 01期

关键词：

D O I：

10.1002/pola.1991.080290111

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-methoxy-5-methylthio-1,4-phenylene vinylene), PMTPV, and copolymers containing both unsubstituted or 2,5-dimethoxy-substituted and 2-methoxy-5-methylthio-1,4-phenylene vinylene units were prepared in thin films from their water-soluble sulfonium salt precursor polymers. Doping of drawn and undrawn films of PMTPV with I2 vapor led to conductivities of 10(-4)-10(-3) S cm-1, which is significantly lower than those reported for poly(2,5-dimethoxy-1,4-phenylene vinylene). Conductivity of I2-doped copolymer films ranges from 10(-3)-10(0) S cm-1 depending on composition.

引用

页码：93 / 100

页数：8

共 28 条

[21] THE CRYSTAL STRUCTURE OF THE 1-1 ADDITION COMPOUND FORMED BY BENZYL SULPHIDE AND IODINE [J].

ROMMING, C .

ACTA CHEMICA SCANDINAVICA, 1960, 14 (10) :2145-2151

[22]

SHIM HK, 1989, MAKROMOL CHEM, V190, P389

[23] NUCLEAR MAGNETIC RESONANCE OF IODINE-ALKYL SULFIDE COMPLEXES [J].

STROM, ET ;

ORR, WL ;

SNOWDEN, BS ;

WOESSNER, DE .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (12) :4017-&

[24] The preparation and germicidal properties of para-hydroxyphenyl alkyl sulfides [J].

Suter, CM ;

Hansen, HL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1932, 54 :4100-4104

[25]

VANDERVEEN J, 1963, RECL TRAV CHIM PAY B, V82, P287

[26] DETERMINATION OF DONOR SITES IN LEWIS ACID ADDUCTS OF ANISOLE + THIOANISOLE [J].

WAYLAND, BB ;

DRAGO, RS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (23) :5240-&

[27]

Wessling, 1968, [No title captured], Patent No. 3401152

[28] DI-(ALPHA-SUBSTITUTED AND BETA-SUBSTITUTED AMINOETHYL)-BENZENES .1. 2,5-BIS-(2-AMINOETHYL)-HYDROQUINONES [J].

WOOD, JH ;

GIBSON, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1949, 71 (02) :393-395

← 1 2 3 →