SYNTHESIS AND ELECTROCONDUCTIVITIES OF POLY(2-METHOXY-5-METHYTHIO-1,4-PHENYLENE VINYLENE) AND COPOLYMERS

被引：21

作者：

JIN, JI ^{[1
]}

PARK, CK ^{[1
]}

SHIM, HK ^{[1
]}

机构：

[1] KOREA ADV INST TECHNOL,DEPT CHEM,TAEJON 305701,SOUTH KOREA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 1991年 / 29卷 / 01期

关键词：

D O I：

10.1002/pola.1991.080290111

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Poly(2-methoxy-5-methylthio-1,4-phenylene vinylene), PMTPV, and copolymers containing both unsubstituted or 2,5-dimethoxy-substituted and 2-methoxy-5-methylthio-1,4-phenylene vinylene units were prepared in thin films from their water-soluble sulfonium salt precursor polymers. Doping of drawn and undrawn films of PMTPV with I2 vapor led to conductivities of 10(-4)-10(-3) S cm-1, which is significantly lower than those reported for poly(2,5-dimethoxy-1,4-phenylene vinylene). Conductivity of I2-doped copolymer films ranges from 10(-3)-10(0) S cm-1 depending on composition.

引用

页码：93 / 100

页数：8

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