[(MU-C(OC2H5))(CO)(4)FE2C((OC2H5)(P-CF3C6H4)(ETA-C7H7))]

被引：60

作者：

CHEN, J ^{[1
]}

ZHENG, PJ ^{[1
]}

YU, Y ^{[1
]}

CHEN, JB ^{[1
]}

机构：

[1] CHINESE ACAD SCI,SHANGHAI INST ORGAN CHEM,SHANGHAI 200032,PEOPLES R CHINA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194000521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of tetracarbonyl-1 kappa(2)C,2 kappa(2)C-mu-{2-[alpha-ethoxy-4-(trifluoromethyl)benzylidene-1 kappa C-alpha]-1(1,2-eta):2(3,4,5,6-eta)-1,3,5-cycloheptatriene}-mu--ethoxymethylidyne-1:2 kappa(2)C-diiron has been determined by X-ray diffraction analysis. The Fe atoms coordinated by carbonyl and cycloheptatriene groups are unsymmetrically bridged by a carbyne ligand. The extensively delocalized bonding may be found over the entire metal-ligand framework.

引用

页码：34 / 37

页数：4

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