Synthesis, Crystal Structure, and Absorption Spectra of 2,2 '-Bipyridine Complexes of Benzoates of Hexavalent U, Np, and Pu

被引：0
作者：
Sokolova, M. N. [1 ]
Bessonov, A. A. [1 ]
Fedoseev, A. M. [1 ]
机构：
[1] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Leninskii Pr 31,Block 4, Moscow 119071, Russia
来源：
RADIOCHEMISTRY | 2012年 / 54卷 / 04期
关键词：
uranium; neptunium; plutonium; coordination compounds; 2,2 '-bipyridine; benzoates; single crystal X-ray diffraction; IR spectra; electronic absorption spectra;
D O I：
10.1134/S1066362212040054
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Complex benzoates [{UO2(C10N2H8)C6H5COO}(2)O-2], [NpO2(C10N2H8)(C6H5COO)(2)], and [PuO2(C10N2H8)(C6H5COO)(2)] (C10N2H8 is 2,2'-bipyridine) were synthesized in the form of single crystals, and their structure was determined by X-ray diffraction analysis. The absorption spectra of the crystalline U(VI), Np(VI), and Pu(VI) complexes were measured and analyzed.
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页码：341 / 345
页数：5
相关论文
共 19 条
  • [1] ACTINIDE STRUCTURAL STUDIES .7. THE CRYSTAL AND MOLECULAR-STRUCTURES OF (2,2'-BIPYRIDYL)DINITRATODIOXO-URANIUM(VI) AND DINITRATODIOXO-NEPTUNIUM(VI), AND DIACETATO-(2,2'-BIPYRIDYL)DIOXO-URANIUM(VI) AND DIOXO-NEPTUNIUM(VI)
    ALCOCK, NW
    FLANDERS, DJ
    BROWN, D
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (05): : 1001 - 1007
  • [2] Neptunium(VI) and Plutonium(VI) pyrazine-2-carboxylates
    Andreev G.B.
    Budantseva N.A.
    Perminov V.P.
    Fedoseev A.M.
    [J]. Radiochemistry, 2005, 47 (1) : 35 - 38
  • [3] [Anonymous], 1998, SAINT PLUS VERS 6 01
  • [4] [Anonymous], 2007, APEX2
  • [5] Bessonov A. A., 2008, RADIOKHIMIYA, V50, P99
  • [6] Cation-cation interaction in crystal structures of Np(V) and Pu(V) benzoate complexes with 2,2′-bipyridine, [NpO2(C10H8N2)(OOCC6H5)]2and [PuO2(C10H8N2) (OOCC6H5)]2
    Charushnikova, I. A.
    Krot, N. N.
    Starikova, Z. A.
    [J]. RADIOCHIMICA ACTA, 2007, 95 (09) : 495 - 499
  • [7] Charushnikova I. A., 2010, RADIOKHIMIYA, V52, P120
  • [8] Charushnikova I.A., 2004, RADIOKHIMIYA, V46, P396
  • [9] Charushnikova I. A., 2004, KOORDINATS KHIM, V30, P554
  • [10] Structure Determination of Neptunium(VI) μ3-Hydroxobenzoate, [(NPO2)2(μ3-OH)2(H5C6COO)2]•2H2O
    Charushnikova, Iraida A.
    Krot, Nikolai N.
    Makarenkov, Vadim I.
    [J]. INORGANIC CHEMISTRY, 2010, 49 (17) : 7611 - 7613
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