BAEYER-VILLIGER OXIDATION OF (3AS AND 3AR, 7AS)-1,2,3A,4,5,6,7,7A-OCTAHYDRO-7A-METHYL [1H]INDEN-1,5-DIONES - SYNTHESIS OF A CHIRAL SYNTHON FOR TOTAL SYNTHESIS OF 14-BETA-ESTRONE

被引：0

作者：

DANIEWSKI, AR ^{[1
]}

KIEGIEL, J ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST ORGAN CHEM,PL-01224 WARSAW,POLAND

来源：

BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY | 1989年 / 37卷 / 7-8期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Regioselectivity of Baeyer-Villiger oxidation of the title compounds 2 and 3 depends on acidity of the reaction medium. Easily accessible compound 2 was transformed into synthon 14 which can be used for total synthesis of 14-beta-estrone.

引用

页码：277 / 281

页数：5

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