A MECHANISM OF LITHIUM STORAGE IN DISORDERED CARBONS

被引：704

作者：

SATO, K ^{[1
]}

NOGUCHI, M ^{[1
]}

DEMACHI, A ^{[1
]}

OKI, N ^{[1
]}

ENDO, M ^{[1
]}

机构：

[1] SHINSHU UNIV,FAC ENGN,NAGANO 380,JAPAN

来源：

SCIENCE | 1994年 / 264卷 / 5158期

关键词：

D O I：

10.1126/science.264.5158.556

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

High-resolution electron microscopy and lithium-7 nuclear magnetic resonance measurements were carried out for a disordered carbon material, prepared by heat treatment of polyphenylene, in which lithium was stored electrochemically. The nuclear magnetic resonance spectrum suggests the existence of Li-2 covalent molecules in the carbon material. This extra covalent site of lithium storage promises extraordinarily high energy density for secondary batteries.

引用

页码：556 / 558

页数：3

共 10 条

[1]

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[2]

CONARD J, 1993, 7 INT S INT COMP LOU, P114

[3] INTERCALATION COMPOUNDS OF GRAPHITE [J].