EPR DETECTION OF ALIPHATIC DISULFIDE ANION RADICALS IN FLUID SOLUTION

被引：10

作者：

CREMONINI, MA ^{[1
]}

LUNAZZI, L ^{[1
]}

PLACUCCI, G ^{[1
]}

机构：

[1] UNIV BOLOGNA, DEPT ORGAN CHEM A MANGINI, RISORGIMENTO 4, I-40126 BOLOGNA, ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1992年 / 04期

关键词：

D O I：

10.1039/p29920000451

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photolysis of alkylthiols (RSH) in EtOH/EtOK in the presence of Bu(t)OOBu(t) yields the disulfide radical anions RSSR.- in conditions suitable for EPR detection in solution over a wide temperature range.

引用

页码：451 / 452

页数：2

共 12 条

[1]

ARMSTRONG DA, 1990, NATO ADV SCI I A-LIF, V197, P341

[2] AN ELECTRON-SPIN-RESONANCE INVESTIGATION OF THE REACTIONS OF GLUTATHIONE, CYSTEINE AND PENICILLAMINE THIYL RADICALS - COMPETITIVE FORMATION OF RSO.,R., RSSR(-.), AND RSS. [J].

BECKER, D ;

SWARTS, S ;

CHAMPAGNE, M ;

SEVILLA, MD .

INTERNATIONAL JOURNAL OF RADIATION BIOLOGY, 1988, 53 (05) :767-786

[3] ROTATIONAL CONFORMERS OF FURAN AND THIOPHENE THIOALDEHYDE ANION RADICALS [J].

BORGHI, R ;

CREMONINI, MA ;

LUNAZZI, L ;

PLACUCCI, G ;

MACCIANTELLI, D .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (22) :6337-6341

[4] MAGNETIC RESONANCE STUDIES OF OXIDATION AND REDUCTION OF ORGANIC MOLECULES BY IONIZING RADIATIONS [J].

BOX, HC ;

FREUND, HG ;

LILGA, KT ;

BUDZINSK.EE .

JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (01) :40-&

[5] THIOALDEHYDE ANION RADICALS [J].

CASARINI, D ;

LUNAZZI, L ;

PLACUCCI, G ;

ISHIDA, T ;

ISHII, A ;

OKAZAKI, R .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (07) :1582-1584

[6]

CHATGILIALGLU C, 1990, SULFUR CTR REACTIVE

[7] ELECTRON-PARAMAGNETIC RESONANCE-SPECTRA OF ALIPHATIC THIOKETYL RADICAL-ANIONS IN FLUID SOLUTION [J].

DAVIES, AG ;

NEVILLE, AG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1992, (02) :171-173

[8]

DUNSTER C, 1990, NATO ADV SCI I A-LIF, V197, P377

[9] ELECTRON-SPIN RESONANCE STUDIES .46. OXIDATION OF THIOLS AND DISULFIDES IN AQUEOUS-SOLUTION - FORMATION OF RS., RSO., RSO2., RSSR.-, AND CARBON RADICALS [J].

GILBERT, BC ;

LAUE, HAH ;

NORMAN, ROC ;

SEALY, RC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1975, (09) :892-900

[10]

Packer J. E., 1974, CHEM THIOL GROUP 2, P481

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