Diaquabis[N-(pyridin-4-yl) isonicotinamide-kappa N] bis(thiocyanato-jN) cobalt(II)

被引：0

作者：

Uebler, Jacob W. ^{[1
]}

LaDuca, Robert L. ^{[1
]}

机构：

[1] Michigan State Univ, Lyman Briggs Coll, Dept Chem, E Lansing, MI 48825 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

single-crystal X-ray study; T = 173 K; mean sigma(C-C) = 0.003 (A)over-circle; R factor = 0.031; wR factor = 0.079; data-to-parameter ratio = 12.6;

D O I：

10.1107/S1600536812024105

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Co(NCS)(2)(C11H9N3O)(2)(H2O)(2)], the octahedrally coordinated Co-II ion lies on a crystallographic inversion center and is bound by two isothiocyanate ligands, two aqua ligands and two N-(pyridin-4-yl) isonicotinamide (4-pina) ligands. The dihedral angle between the aromatic rings in the 4-pina ligand is 8.98 (11)degrees. In the crystal, the individual molecular units are aggregated in three dimensions by OH center dot center dot center dot N, O-H center dot center dot center dot S and N-H center dot center dot center dot S hydrogen-bonding pathways.

引用

页码：M867 / +

页数：8

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