ELECTRON IMPACT STUDIES .40. NEGATIVE-ION MASS SPECTRA OF ORGANOSULPHUR COMPOUNDS - THIOGLYCOLLIC ACIDS AND ARYLSULPHINYLAMINES

被引：23
作者：
BOWIE, JH
DUUS, F
LAWESSON, SO
LARSSON, FCV
MADSEN, JO
机构：
[1] Department of Organic Chemistry, University of Adelaide, Adelaide, SA, 5001
[2] Department of Organic Chemistry, Aarhus University, Aarhus C
来源：
AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 01期
基金：
澳大利亚研究理事会;
关键词：
D O I：
10.1071/CH9690153
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The negative-ion mass spectra of thioglycollic esters and S-alkylthioglycollic acids exhibit ions produced by simple cleavage and/or cleavage with hydrogen rearrangement. Similar spectra of arylsulphinylamines show pronounced molecular ions together with simple cleavage fragments. No skeletal-rearrangement fragments are present in the negative-ion spectra, in marked contrast with those observed in the corresponding positive-ion spectra. © 1969, CSIRO. All rights reserved.
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页码：153 / &
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