PALLADIUM-CATALYZED SYNTHESIS OF THE CINNAMIC METHYL-ESTER FROM STYRENE, CARBON-MONOXIDE AND METHANOL

被引：22

作者：

COMETTI, G ^{[1
]}

CHIUSOLI, GP ^{[1
]}

机构：

[1] UNIV PARMA,IST CHIM ORGAN,I-43100 PARMA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 181卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)82840-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methyl cinnamate, together with dimethyl phenylsuccinate, is obtained from carbomethoxylation of styrene catalysed by a palladium salt, coupled with a copper(II) reoxidizing system and an alkali metal salt, at room temperature and lower than atmospheric pressures of carbon monoxide. © 1979.

引用

页码：C14 / C16

页数：3

共 10 条

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[2] CHIUSOLI GP, 1968, CHEM IND-LONDON, P977
[3] COMETTI G, 1978, Patent No. 22645
[4] FENTON DM, 1972, CHEM TECHNOL, P220
[5] NOBLE-METAL CATALYSIS .3. PREPARATION OF DIALKYL OXALATES BY OXIDATIVE CARBONYLATION
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[6] MECHANISM OF ARYLATION AND CARBOMETHOXYLATION OF OLEFINS WITH ORGANOPALLADIUM COMPOUNDS
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[7] PALLADIUM(II) CATALYZED OLEFIN CARBONYLATION REACTION - MECHANISMS AND SYNTHETIC UTILITY
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (07) : 1810 - 1823
[8] NEW PALLADIUM CARBONYL CLUSTERS - X-RAY CRYSTAL-STRUCTURE OF [PD4(CO)4(OAC)4].(ACOH)2
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STROMNOVA, TA
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (01) : 27 - 28
[9] ALKOXY CARBONYL-COMPLEXES OF PALLADIUM AND THEIR ROLE IN ALCOHOL CARBONYLATION
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 154 (03) : 323 - 326
[10] Tsuji J, 1964, J AM CHEM SOC, V86, P2095

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