THE SIGNIFICANCE OF MEDIUM IN THE REACTION OF ANIONIC SIGMA-COMPLEXES

被引：0
作者：
GLAZ, AJ
GITIS, SS
KAMINSKY, AY
机构：
来源：
IZVESTIYA SIBIRSKOGO OTDELENIYA AKADEMII NAUK SSSR SERIYA KHIMICHESKIKH NAUK | 1990年 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A multiple influence of medium upon the direction and the rate of activated nucleophilic substitution reaction in the set of aromatic polynitrocompounds has been found. The basicity of the solvent exerts most of the influence. Its polarity influence the establishment of ionic-pair equilibrium and herwith predetermines the nature of the reacting particles, while the interaction of the solvent's components and its structure influence their activity.
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页码：100 / 109
页数：10
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