CRYSTAL STRUCTURE OF METHYLMERCURY(2) CYANIDE

被引：38

作者：

MILLS, JC

PRESTON, HS

KENNARD, CHL

机构：

[1] Department of Chemistry, University of Queensland, Brisbane

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 14卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)92636-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of methylmercury(II) cyanide, CH3HgCN, has been determined by three dimensional X-ray and neutron diffraction. The compound crystallises out in an orthorhombic unit cell, space group Pnma; cell dimensions (X-ray) a = 9.12(2), b = 6.14(2), c = 7.01(2) Å; cell dimensions (neutron), a = 9.11(2), b = 6.14(2), c = 7.01(2) Å. With four molecules of CH3HgCN per unit cell, all atoms, except the hydrogens, are on mirror planes at y = 1 4, 3 4. Interatomic distances are: HgC (cyanide) = 2.05(1), HgC (methyl) = 2.08(2), and CN = 1.14(1) Å. Refinement indicates that the methyl group is rotating. © 1968.

引用

页码：33 / &

共 24 条

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