COMPLEXES OF TRANSITION-METALS AND HETEROALLENES .23. REACTIONS OF THE CLUSTER COMPLEX (THIOKETENE)FE2(CO)6 WITH ARSA-CHELATE LIGANDS

被引：4

作者：

WIEDERHOLD, M ^{[1
]}

BEHRENS, U ^{[1
]}

机构：

[1] UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,MARTIN LUTHER KING PL 6,W-2000 HAMBURG 13,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 384卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)87052-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster complex (thioketene)Fe2(CO)6 (2) reacts with ARPHOS (5) to give the adduct (thioketene)Fe2(CO)6(arphos) (7). In solution complex 7 very slowly cleaves CO to form the compound (thioketene)Fe2(CO)5 (arphos) (8). Heating or irradiation of 8 yields a dinuclear complex (thioketene)2Fe2(CO)4(arphos) (9) having two thioketene ligands in the molecule. Reaction of the cluster 2 with DIARS (6) gives the complex (thioketene)Fe2(CO)5 (diars) (13). The crystal structures of 7 and 13 have been determined by X-ray diffraction. © 1990.

引用

页码：49 / 59

页数：11

共 45 条

[1] TRANSITION-METAL THIOKETENE COMPLEXES .8. REACTIONS OF CLUSTER COMPLEXES (THIOKETENE)FE2(CO)6 WITH PHOSPHANES - STRUCTURE AND PROPERTIES OF THIOKETENE-IRON COMPLEXES
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WORMSBACHER, D
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 284 (03) : 353 - 377
[2] Reactions of anions [(μ-PhSe)(μ-CO)Fe2(CO)6]- and {[μ-SeZSe-μ][(μ-CO)Fe2(CO)6]2}2- with various electrophiles to give the corresponding new linear and macrocyclic cluster complexes
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[3] COMPLEX COMPOUNDS OF METALS WITH NITROGEN-CONTAINING LIGANDS .24. COMPLEXES OF TRANSITION METALS WITH 2-ARENEAZO DERIVATIVES OF IMIDAZOLE SERIES .23.
GARNOVSKII, AD
KUZNETSO.LI
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OSIPOV, OA
KOLODYAZ.YV
MINKIN, VI
BREN, VA
SIMONOV, AM
AVDYUNIN.NI
ZHURNAL OBSHCHEI KHIMII, 1971, 41 (08): : 1829 - +
[4] Models of the iron-only hydrogenase:: Reactions of [Fe2(CO)6(μ-pdt)] with small bite-angle diphosphines yielding bridge and chelate diphosphine complexes [Fe2(CO)4(diphosphine)(μ-pdt)]
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (18) : 3957 - 3968
[5] Synthesis of bridging carbyne butterfly Fe/Se cluster complexes via reaction of complex anions [(μ-RSe)(μ-CO)Fe2(CO)6]- -: Crystal structure of (μ-EtOC)(μ-p-MeC6H4Se)Fe2(CO)6
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[6] Unexpected preparation of butterfly Fe/S cluster complexes containing a quaternary phosphorus atom via reactions of the anions (μ-RS)(μ-S-)Fe2(CO)6 and (μ-RS)(μ-S-)[Fe2(CO)6]2(μ-S) with diphenylchlorophosphine
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ORGANOMETALLICS, 2005, 24 (01) : 16 - 19
[7] General synthetic route to double-butterfly Fe/S cluster complexes via reactions of the dianions {[(μ-CO)Fe2(CO)6]2(μ-SZS-μ)}2- with electrophiles
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ORGANOMETALLICS, 2004, 23 (04) : 823 - 831
[8] TRANSITION-METAL-HETEROALLENE COMPLEXES .17. REACTIONS OF AZA-ALLYL COMPLEXES (KETENE-IMINE)FE2(CO)6 WITH PHOSPHANES
SIELISCH, T
BEHRENS, U
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 327 (01) : 85 - 99
[9] SULFUR-CONTAINING METAL-COMPLEXES .23. SYNTHESIS OF NEW COMPLEXES CONTAINING THE FE2(CO)6S2 BUTTERFLY UNIT - CRYSTAL AND MOLECULAR-STRUCTURE OF [FE2(CO)6(MU-S2P(C6H4OME-P)FE(CO)4)], DETERMINED FROM 2 DIFFERENT CRYSTAL MODIFICATIONS
KRUGER, GJ
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 280 (02) : 241 - 251
[10] REACTIONS OF 2-FURYL, 2-THIENYL, AND N-METHYL-2-PYRROLYL MERCURIALS WITH [ET3NH][(MU-CO)(MU-RS)FE2(CO)6] COMPLEXES - SYNTHESIS OF FE2(CO)6 COMPLEXES WITH BRIDGING ETA(1)-ETA(2)-FURYL AND THIENYL LIGANDS
SEYFERTH, D
ANDERSON, LL
VILLAFANE, F
COWIE, M
HILTS, RW
ORGANOMETALLICS, 1992, 11 (10) : 3262 - 3271

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