ALTERNATIVE SYNTHESES OF BRIDGEHEAD POLYCYCLIC 1,2-DIAMINES AND 2-AMINOALCOHOLS FROM DI-OXIMES AND MONO-OXIMES OF SOME BICYCLIC DIKETONES - HIGHLY IMPROVED SYNTHESIS OF TRICYCLO[3.3.1.0(3,7)]NONANE-3,7-DIAMINE

被引：15

作者：

CAMPS, P

MUNOZTORRERO, D

机构：

[1] Laboratorio de Química Farmacéutica, Facultad de Farmacia, Universidad de Barcelona, E-08028 Barcelona, Av. Diagonal s/n

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(00)76863-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bridgehead polycyclic 1,2-diamines 4a and 4b have been obtained from dioximes 2a and 26, respectively, by two alternative procedures: a) m-chloroperbenzoic acid oxidative coupling to 3a and 3b, followed bp reduction with aluminum amalgam, and b) reductive coupling with aluminum amalgam. Similarly, the related 2-aminoalcohols 9a and 9b have been obtained from rite corresponding monooximes 7a and 7b.

引用

页码：3187 / 3190

页数：4

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