Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)

被引：0
|
作者：
Kani, Ibrahim [1 ]
机构：
[1] Anadolu Univ, Dept Chem, Fac Sci, TR-26470 Eskisehir, Turkey
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; manganese(II) complex; benzoylbenzoate; 2,2'-bipyridine; hydrogen bonding;
D O I：
10.1107/S2056989015023671
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Mn-2(C6H5COC6H4COO)(2)(C10H8N2)(4)](ClO4)(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn-II atoms are bridged by two 0 atoms of two different 2-benzoyl-benzoate ligands, each Mn-II atom being further coordinated by two 2,2'-bipyridine (bipy) ligands in a distorted octahedral environment. Within the binuclear molecule, the Mn center dot center dot center dot Mn separation is 4.513 (7) angstrom. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions link the molecules into a three-dimensional network.
引用
收藏
页码：M265 / U414
页数：11
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