Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)

被引：0

作者：

Kani, Ibrahim ^{[1
]}

机构：

[1] Anadolu Univ, Dept Chem, Fac Sci, TR-26470 Eskisehir, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷

关键词：

crystal structure; manganese(II) complex; benzoylbenzoate; 2,2'-bipyridine; hydrogen bonding;

D O I：

10.1107/S2056989015023671

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Mn-2(C6H5COC6H4COO)(2)(C10H8N2)(4)](ClO4)(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn-II atoms are bridged by two 0 atoms of two different 2-benzoyl-benzoate ligands, each Mn-II atom being further coordinated by two 2,2'-bipyridine (bipy) ligands in a distorted octahedral environment. Within the binuclear molecule, the Mn center dot center dot center dot Mn separation is 4.513 (7) angstrom. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions link the molecules into a three-dimensional network.

引用

页码：M265 / U414

页数：11

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