OPTICALLY-ACTIVE TRANSITION-METAL COMPLEXES .100. PHOTOCHEMICALLY INDUCED CIS-TRANS-ISOMERIZATION IN OPTICALLY-ACTIVE PHOSPHIDO BRIDGED IRON COMPLEXES OF THE TYPE (CPFE(MU-PR2)CO)2 AND (CP2FE2(MU-H) (MU-PR2) (CO)2)

被引：10

作者：

BRUNNER, H

PETER, H

机构：

[1] Institut für Anorganische Chemie, Universität Regensburg, D-8400 Regensburg

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 393卷 / 03期

关键词：

D O I：

10.1016/0022-328X(90)85172-U

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Starting from the optically active PH phospholanes diopholane HPDph and tarpholane HPTph as well as HPMePh the phosphido bridged iron complexes 1-4 have been prepared and characterized. Complexes 1-4 form mixtures of cis-trans isomers with respect to the Cp and CO ligands. In addition, the complexes trans-2 and trans-3 exist as two diastereomers differing only in the configuration of the Fe atoms. Complexes 1-4 undergo in solution a photochemically induced cis-trans isomerization process, for which a CO dissociation is discussed. © 1990.

引用

页码：411 / 422

页数：12

共 19 条

[1]

AHMAD M, 1966, Z NATURFORSCH PT B, VB 21, P289

[2] ASYMMETRIC CATALYSIS .33. NEW OPTICALLY-ACTIVE PHOSPHOLANES DERIVED FROM TARTARIC ACID [J].