SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES)

被引：30

作者：

ANDO, W

OHTAKI, T

KABE, Y

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of bis[bis(trimethylsilyl)methyl]-germylene (1) with N-(azidosilyl)germanimines 3a,b at room temperature gave bis(germanimines) 4a,b in quantitative yield whose structures have been confirmed by single-crystal X-ray diffraction. The photolysis of 4a gave the cyclic silanimine 6 as an unexpected product.

引用

页码：434 / 435

页数：2

共 15 条

[11] AN INTRAMOLECULARLY LEWIS-BASE-STABILIZED GE=N-COMPOUND AND A RELATED GE-FE COMPLEX
VEITH, M
BECKER, S
HUCH, V
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (02): : 216 - 218
[12] SILICON-COMPOUNDS WITH STRONG INTRAMOLECULAR STERIC INTERACTIONS .37. REACTIONS OF STERICALLY HINDERED SILYLENES WITH TRI-TERT-BUTYLSILYL AZIDE
WEIDENBRUCH, M
BRANDROTH, B
POHL, S
SAAK, W
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 379 (03) : 217 - 222
[13] THE PHOTOCHEMISTRY OF MATRIX-ISOLATED DI-TERT-BUTYLDIAZIDOSILANE - OBSERVATION OF DI-TERT-BUTYLSILYLENE AND N,N'-DI-TERT-BUTYLSILANEDIIMINE
WELSH, KM
MICHL, J
WEST, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) : 6689 - 6696
[14] UNSATURATED-COMPOUNDS OF SILICON AND GROUP HOMOLOGS .8. UNSATURATED SILICON AND GERMANIUM COMPOUNDS OF THE TYPES R2E=C(SIR3)2 AND R2E=N(SIR)3 (E = SI, GE)
WIBERG, N
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 273 (02) : 141 - 177
[15] SILYLAZIDE .V. DARSTELLUNG EIGENSCHAFTEN UND STRUKTUR EINIGER SILYLAZIDE
WIBERG, N
NERUDA, B
[J]. CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (03): : 740 - &

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