SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES)

被引：31

作者：

ANDO, W

OHTAKI, T

KABE, Y

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 02期

关键词：

D O I：

10.1021/om00014a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of bis[bis(trimethylsilyl)methyl]-germylene (1) with N-(azidosilyl)germanimines 3a,b at room temperature gave bis(germanimines) 4a,b in quantitative yield whose structures have been confirmed by single-crystal X-ray diffraction. The photolysis of 4a gave the cyclic silanimine 6 as an unexpected product.

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页码：434 / 435

页数：2

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