TOWARDS A MOLECULAR THEORY OF POLYMER BLENDS

被引:1
|
作者
FREED, KF [1 ]
DUDOWICZ, J [1 ]
机构
[1] UNIV CHICAGO,DEPT CHEM,CHICAGO,IL 60637
关键词
D O I
10.1002/masy.19940780105
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The importance of including specific monomer structures, local correlations. and 'equation of state effects' into the statistical thermodynamics of polymer blends is accomplished by developing and applying the Lattice cluster theory. This new theory provides systematic corrections to Flory-Huggins theory from local correlations and describes polymers as containing structured monomers that extend over several lattice sites.
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页码:29 / 40
页数:12
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