SILVER COORDINATION AND ORGANOMETALLIC COMPOUNDS: CLASSIFICATION AND ANALYSIS OF CRYSTALLOGRAPHIC AND STRUCTURAL DATA

被引：31

作者：

Holloway, Clive E. ^{[1
]}

Melnik, Milan ^{[2
]}

Nevin, W. Andrew ^{[3
]}

Liu, Wei ^{[4
]}

机构：

[1] York Univ, Dept Chem, N York, ON M3J 1P3, Canada

[2] Slovak Tech Univ, Dept Inorgan Chem, Bratislava 81237, Slovakia

[3] Kaneka Corp, Cent Res Labs, Hyogo Ku, Kobe, Hyogo 652, Japan

[4] Yangzhou Teachers Coll, Dept Chem, Yangzhou, Jiangsu, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1995年 / 35卷 / 1-2期

关键词：

review; silver; crystallography; structures;

D O I：

10.1080/00958979508033088

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review summarizes the data for almost six hundred silver coordination and organometallic compounds, with the silver atom occurring in oxidation states of +1, +2, and two examples of +3 in a square-planar environment. The +2 oxidation state is found in digonal, square-planar, tetrahedral and hexa-coordinated environments. The +1 oxidation state is by far the most common in various geometries from two to seven. The nuclearity range from mono- to polynuclear utilizing a variety of ligand types. There are several examples of distortion isomerism, and a few examples of polymerization isomerism. Correlations between bond lengths, bond angles, ligating atom radius and silver oxidation state are discussed.

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页码：85 / 178

页数：94

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